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Thiopyran route to polypropionates : simultaneous-two directional and enantiotopic group selective aldol reactions
The sequential aldol reactions of thiopyran derivatives 112 and 119 to rapidly generate hexapropionate building blocks in two carbon-carbon forming steps has been well studied within the Ward group. An extension of this ...
Building Carbohydrates on Dioxanone Scaffold
Protected DHA units, known as dioxanones, are interesting compound which can be used as the building blocks for synthesis of polyoxygenated natural products. The direct aldol reaction is employed for converting of those ...