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Relaxation in the electrical properties of amorphous selenium based photoconductors

dc.contributor.advisorKasap, S.O.en_US
dc.creatorAllen, Christopher S.en_US
dc.date.accessioned2009-04-14T18:00:26Zen_US
dc.date.accessioned2013-01-04T04:29:09Z
dc.date.available2010-04-15T08:00:00Zen_US
dc.date.available2013-01-04T04:29:09Z
dc.date.created2009-04en_US
dc.date.issued2009-04-15en_US
dc.date.submittedApril 2009en_US
dc.description.abstractTime-of-Flight (TOF) and Interrupted-Field Time-of-Flight (IFTOF) measurements were performed repeatedly on several different samples of amorphous Selenium (a-Se) alloys as they aged from deposition or after annealing above the glass transition temperature (Tg) in order to examine the relaxation of the electrical properties. The mobility was found to relax slightly, but the relaxation did not fit well to a stretched exponential. The increase in the mobility for electrons was significantly more than the increase in mobility for holes in all sample compositions measured. For electrons, the mobility increased by 20-40%, whereas for holes, the mobility only increased by less than 10%. The relaxation of the lifetime, on the other hand, fit well to a stretched exponential. Furthermore, the overall increase in lifetime as it relaxed was much greater than the increase in the mobility. The average increase in lifetime was 85% for holes and 45% for electrons. The stretched exponential fits consisted of two important factors: the structural relaxation time τsr and the stretching factor β. For a given a-Se alloy, τsr was approximately the same for relaxation from both immediately after sample deposition, and annealing above Tg, indicating that the relaxation is readily repeatable and has the same physical origin. The relaxation was found to be dependent on the a-Se alloy composition. While the general shape of the relaxation was consistently a stretched exponential, τsr increased with increasing arsenic (As) concentration in the alloy, while β remained constant between 0.6-0.7. Additionally, τsr was found to be the same for both electron and hole relaxations for a given composition. Thus, the relaxation in both the electron and hole lifetime seems to be controlled by the same structural relaxation process, that is, the electron and hole traps are structural in origin.en_US
dc.identifier.urihttp://hdl.handle.net/10388/etd-04142009-180026en_US
dc.language.isoen_USen_US
dc.subjectelectricalen_US
dc.subjectdetectorsen_US
dc.subjectrelaxationen_US
dc.subjectSeleniumen_US
dc.subjectstructuralen_US
dc.titleRelaxation in the electrical properties of amorphous selenium based photoconductorsen_US
dc.type.genreThesisen_US
dc.type.materialtexten_US
thesis.degree.departmentElectrical Engineeringen_US
thesis.degree.disciplineElectrical Engineeringen_US
thesis.degree.grantorUniversity of Saskatchewanen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Engineering (M.Eng.)en_US

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