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The versatility of palladium systems: from palladacycles to cyclic peptides and beyond

Date

2015-08-12

Journal Title

Journal ISSN

Volume Title

Publisher

ORCID

Type

Thesis

Degree Level

Masters

Abstract

This work started with the aim to synthesize monomeric ring-opened analogues of the palladacycles [(iminoisoidoline)PdCl(PCy3)] incorporating iminoisoindoline and phosphine ligands, and evaluate their catalytic activities in C-C coupling reactions compared to their monomeric palladacyclic precursors. This project further evolved to investigate cyclic peptides derived from flaxseed oil as alternative ligands in palladium coordination chemistry for applications in C-C coupling reactions. During the course of our studies, we observed that cyclic peptides derived from flaxseed oil had a high affinity for first row transition metals.

Description

Keywords

palladacycle, cyclic peptide, suzuki reaction

Citation

Degree

Master of Science (M.Sc.)

Department

Chemistry

Program

Chemistry

Advisor

Part Of

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DOI

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