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Preparation & Characterization of n-Type Amorphous Selenium Films as Blocking Layers in a-Se X-ray Detectors

dc.contributor.advisorKasap, Safaen_US
dc.contributor.committeeMemberOguocha, Ikechukwukaen_US
dc.contributor.committeeMemberChen, Lien_US
dc.contributor.committeeMemberTeng, Danielen_US
dc.creatorDash, Ishaen_US
dc.date.accessioned2009-08-04T10:31:57Zen_US
dc.date.accessioned2013-01-04T04:50:56Z
dc.date.available2010-08-17T08:00:00Zen_US
dc.date.available2013-01-04T04:50:56Z
dc.date.created2009en_US
dc.date.issued2009en_US
dc.date.submitted2009en_US
dc.description.abstractThe "n-like layer" is important in multilayer layer amorphous selenium (a-Se) based Xray detector structures because it blocks the injection of holes from the positive electrode. The dark current in these devices is controlled primarily by hole injection, and the introduction of the n-like layer to block hole injection was a key development in the commercialization of a-Se X-ray detectors. An n-like a-Se layer is defined as a layer in which the electron range is much greater than the hole range, μₑτₑ >> μₕτₕ, where τ and μ are the lifetime and drift mobility of the charge carriers and the subscript e and h represent electrons and holes. This thesis examines the effect of doping a-Se with Group II elements (in particular Mg) towards finding a better n-like layer – that with relatively long electron range (drift mobility × lifetime) , trap limited hole transport and which is stable against crystallization. Conventional Time of Flight (TOF) and Interrupted Field Time of Flight (IFTOF) transient photoconductivity measurements were used to characterize the electron and hole transport in various Group II doped a-Se layers. The dependence of the electron and hole lifetimes and drift mobilities on the composition of the n-like layer was examined. The addition of Group II materials converts the a-Se starting material from p-like into n-like. It was found that increasing the concentration of Mg increases the electron range while limiting the hole range by modifying the population of deep traps. The addition of As further limits the hole transport but does not alter the electron range. The clear reproducibility of the thermal properties obtained from the Differential Scanning Calorimetry (DSC) implies that small amounts of Mg can be used as a suitable n-type dopant.en_US
dc.identifier.urihttp://hdl.handle.net/10388/etd-08042009-103157en_US
dc.language.isoen_USen_US
dc.subjectAmorphous Seleniumen_US
dc.subjectn-layersen_US
dc.subjectX-ray Deetectorsen_US
dc.titlePreparation & Characterization of n-Type Amorphous Selenium Films as Blocking Layers in a-Se X-ray Detectorsen_US
dc.type.genreThesisen_US
dc.type.materialtexten_US
thesis.degree.departmentElectrical Engineeringen_US
thesis.degree.disciplineElectrical Engineeringen_US
thesis.degree.grantorUniversity of Saskatchewanen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Science (M.Sc.)en_US

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