Browsing by Author "Pan, Yuanming"
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Item Recommended nomenclature of epidote-group minerals(GeoScience World, 2006) Armbruster, Thomas; Bonazzi, Paola; Akasaka, Mashide; Bermanec, Vladimir; Chopin, Christian; Giere, Reto; Heuss-Aßbichler, Soraya; Liebscher, Axel; Menchetti, Silvio; Pan, Yuanming; Pasero, MarcoEpidote-group minerals are monoclinic in symmetry and have topology consistent with space group P21/m and the general formula A2M3[T2O7][TO4](O,F)(OH,O). Zoisite is an orthorhombic polymorph of clinozoisite Ca2Al3[Si2O7][SiO4]O(OH) and is thus not considered a member of the epidote-group. Epidote-group minerals are divided into three subgroups. (1) Members of the clinozoisite subgroup are derived from the mineral clinozoisite Ca2Al3[Si2O7][SiO4]O(OH) by homovalent substitutions only. The key cation- and anion-sites are A1 = M2+, A2 = M2+, M1 = M3+, M2 = M3+, M3 = M3+, O4 = O2-, O10 = (OH)-. In other words, the dominant valence as listed above must be maintained. (2) Members of the allanite subgroup are REE-rich minerals typified by the eponymous mineral “allanite”. This subgroup may be derived from clinozoisite by homovalent substitutions and one coupled heterovalent substitution of the type A2(REE)3+ + M3M2+ → A2Ca2+ + M3M3+. Thus the valences on the key sites are: A1 = M2+, A2 = M3+, M1 = M3+, M2 = M3+, M3 = M2+, O4 = O2-, O10 = (OH)-. (3) Members of the dollaseite subgroup are REE-rich minerals typified by the eponymous mineral “dollaseite”. This subgroup may be derived from clinozoisite by homovalent substitutions and two coupled heterovalent substitutions of the type A2(REE)3+ + M3M2+ → A2Ca2+ + M3M3+ and M1M2+ + O4F-→ M1M3+ + O4O-2. Thus the valences on the key sites are: A1 = M2+, A2 = M3+, M1 = M2+, M2 = M3+, M3 = M2+, O4 = F-, O10 = (OH)-. The key cation-sites M3 and A1 (and, in principle, M2) determine the root name. In both clinozoisite and allanite subgroups no prefix is added to the root name if M1 = Al. The prefixes ferri, mangani, chromo, and vanado indicate dominant Fe3+, Mn3+, Cr3+, and V3+ on M1, respectively. In the dollaseite subgroup no prefix is added to the root name if M1 = Mg. Otherwise a proper prefix must be attached; the prefixes ferro and mangano indicate dominant Fe2+ and Mn2+ at M1, respectively. The dominant cation on A2 (other than Ca) is treated according to the Extended Levinson suffix designation. This simple nomenclature requires renaming of the following approved species: Niigataite (old) = clinozoisite-(Sr) (new), hancockite (old) = epidote-(Pb) (new), tweddillite (old) = manganipiemontite-(Sr) (new). Minor modifications are necessary for the following species: Strontiopiemontite (old) = piemontite-( Sr) (new), androsite-(La) (old) = manganiandrosite-(La) (new). Before a mineral name can be assigned, the proper subgroup has to be determined. The determination of a proper subgroup is made by the dominating valence at M3, M1, and A2 expressed as M2+ and or M3+, not by a single, dominant ion (i.e., Fe2+, or Mg, or Al). In addition, the dominant valence on O4: X- or X2- must be ascertained. [M2+]A2 > 0.50, [M3+]M3 > 0.50 → clinozoisite subgroup, [M3++ M4+]A2 > 0.50, [M2+]M3 > 0.50 → allanite subgroup, {[M2+]M3+M1 – [M3++ M4+]A2 } > 0.50 and [X-]O4 > 0.5 → dollaseite subgroup. Coupled heterovalent substitutions in epidote-group minerals require a special application of the so-called 50 % rule in solid-solution series. (1) Clinozoisite subgroup: The dominant trivalent cation on M3 determines the name, whereas the A2 cation appearing in the suffix has to be selected from among the divalent cations. (2) Allanite and dollaseite subgroups: For the sites involved in the charge compensation of a heterovalent substitution in A2 and O4 (i.e. M3 in the allanite subgroup; M3 and M1 in the dollaseite subgroup), identification of the relevant end-member formula must take into account the dominant divalent charge-compensating octahedral cation (M2+) and not the dominant cation in these sites. Formal guidelines and examples are provided in order to determine a mineral “working name” from electron-microprobe analytical data.Item Widespread Archean basement beneath the Yangtze craton(GeoScience World, 2006) Zheng, Jianping; Griffin, William L; O’Reilly, Suzanne Y.; Zhang, Ming; Pearson, Norman; Pan, YuanmingThe age distribution of the crust is a fundamental parameter in modeling continental evolution and the rate of crustal accretion through Earth’s history, but this is usually estimated from surface exposures. The exposed Yangtze craton in eastern China consists mainly of Proterozoic rocks with rare Archean outcrops. However, the U-Pb ages and Hf isotope systematics of xenocrystic zircons brought to the surface in lamproite diatremes from three Proterozoic outcrop areas of the craton suggest the widespread presence of unexposed Archean basement, with zircon age populations of 2900–2800 Ma and 2600– 2500 Ma and Hf model ages of 2.6 to ca. 3.5 Ga or older. The zircons also record thermal events reworked on the craton ca. 2020 Ma (remelting of older crust) and 1000–850 Ma (addition of juvenile mantle material). The observation of deep crust significantly older than the upper crust will require revision of models for the rates of crustal generation through time.