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Browsing College of Engineering by Author "Niu, Catherine"

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    Experimental and Modeling Studies of Torrefaction of Spent Coffee Grounds and Coffee Husk: Effects on Surface Chemistry and Carbon Dioxide Capture Performance
    (ACS Publications, 2022) Mukherjee, Alivia; OKOLIE, JUDE; Niu, Catherine; Dalai, Ajay K.
    Torrefaction of biomass is a promising thermochemical pretreatment technique used to upgrade the properties of biomass to produce solid fuel with improved fuel properties. A comparative study of the effects of torrefaction temperatures (200, 250, and 300 °C) and residence times (0.5 and 1 h) on the quality of torrefied biomass samples derived from spent coffee grounds (SCG) and coffee husk (CH) were conducted. An increase in torrefaction temperature (200–300 °C) and residence time (0.5–1 h) for CH led to an improvement in the fixed carbon content (17.9–31.8 wt %), calorific value (18.3–25 MJ/kg), and carbon content (48.5–61.2 wt %). Similarly, the fixed carbon content, calorific value, and carbon content of SCG rose by 14.6–29 wt %, 22.3–30.3 MJ/kg, and 50–69.5 wt %, respectively, with increasing temperature and residence time. Moreover, torrefaction led to an improvement in the hydrophobicity and specific surface area of CH and SCG. The H/C and O/C atomic ratios for both CH- and SCG-derived torrefied biomass samples were in the range of 0.93–1.0 and 0.19–0.20, respectively. Moreover, a significant increase in volatile compound yield was observed at temperatures between 250 and 300 °C. Maximum volatile compound yields of 11.9 and 6.2 wt % were obtained for CH and SCG, respectively. A comprehensive torrefaction model for CH and SCG developed in Aspen Plus provided information on the mass and energy flows and the overall process energy efficiency. Based on the modeling results, it was observed that with increasing torrefaction temperature to 300 °C, the mass and energy yield values of the torrefied biomass samples declined remarkably (97.3% at 250 °C to 67.5% at 300 °C for CH and 96.7% at 250 °C to 75.1% at 300 °C for SCG). The SCG-derived torrefied biomass tested for CO2 adsorption at 25 °C had a comparatively higher adsorption capacity of 0.38 mmol/g owing to its better textural characteristics. SCG would need further thermal treatment or functionalization to tailor the surface properties to attract more CO2 molecules under a typical post-combustion scenario.
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    Techno – Economic analysis of activated carbon production from spent coffee grounds: Comparative evaluation of different production routes
    (Elsevier, 2022) Mukherjee, Alivia; OKOLIE, JUDE; Niu, Catherine; Dalai, Ajay K.
    Activated carbon (AC) has gained immense popularity owing to its excellent physicochemical properties and its ability to remove carbon dioxide (CO2) from flue gas stream. This study examines the potential of spent coffee grounds (SCG) as a precursor for activated carbon (AC) production via prominent thermochemical conversion technologies. Different production routes, such as slow pyrolysis, activation, and deep eutectic solvent (DES) functionalization were compared in terms of their economic viability. Three scenarios (Scenario 1–3) involving combinations of the technologies and production routes were evaluated. Scenario 1 comprises of slow pyrolysis, CO2 activation and flue gas recycling for activation. Scenario 2 includes flue gas combustion while the third scenario comprise of flue gas combustion and DES impregnation. All processes were simulated with Aspen plus, while a detailed cash flow analysis was used to estimate the profitability parameters. The price of AC was found to be the most crucial determinant of an AC production plant’s viability and feasibility. The minimum selling price (MSP) of AC samples produced from scenarios 1,2 and 3 are U.S $0.15/kg, $0.21/kg, $0.28/kg respectively. The price of pristine AC and DES treated AC were lower than the commercially available activated carbon (U.S $0.45/kg).