Torrefaction and Steam Explosion of Selected Biomass for Biofuel Production
Date
2024-01-31
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
ORCID
0000-0002-1069-0020
Type
Thesis
Degree Level
Doctoral
Abstract
Lignocellulosic biomass has demonstrated great potential as feedstock for pellet production, notwithstanding the fact that the industrial production of pellet is faced with some economic challenges. Pretreatment research has been focused on identifying, evaluating, developing, and demonstrating promising approaches that enhance the physiochemical and mechanical properties of biomass. Assessment of biomass pretreatment processes depends on a parameter called the severity factor, which is defined as the combined effect of temperature and residence time. This study summarizes pretreatment processing methods, namely, steam explosion and torrefaction of selected biomass feedstocks (sawdust and oat straw), processing characteristics, and product properties. The study also discusses the economics of densifying biomass, outstanding challenges, the potential for industrial applications of biomass-pretreated products, and global trends in biomass utilization. Steam explosion pretreatment of sawdust and oat straw was conducted under 3 stages: mild, medium, and severe conditions. The effects of temperature, time, and moisture content on the physiochemical and mechanical properties of pellets formed were examined. The p-values of the regression models for all the response variables (dimensional stability, tensile strength, and pellet density) studied were significant (p < 0.05), except for the pellet density of steam-pretreated oat straw pellets. The interaction of these three factors did not significantly affect the response variables of oat straw pellets. Microstructural examination of the pellets from steam-pretreated biomass revealed that the material contained particles that were more closely bonded and featured a cemented surface with fewer pores when compared to particles from untreated oat straw and sawdust.
Microwave-assisted torrefaction was conducted on white spruce sawdust (WSS) at temperatures of 200 °C, 250 °C, and 300 °C and retention times of 5 min, 7 min, and 9 min in an inert environment. Torrefaction pretreatment is a mild form of pyrolysis that has the potential to produce high-quality raw material for making biofuel that serves as a replacement for coal in the bioenergy industry. The torrefaction process produces a solid carbon, commonly known as biochar, and condensable (torrefaction liquid (TL)) and non-condensable gases. In this study, torrefaction characteristics were investigated to observe its effects on the thermal and physiochemical properties of the pellets produced. During the torrefaction process, a significant mass loss associated with the decomposition of hemicellulose was observed. The hemicellulose content drastically reduced to approximately 1.8% from 19.25% and the cellulose content was reduced by approximately 10%, while the lignin gained approximately 35% as the severity increased. This led to an improvement in the higher heating value (HHV), hydrophobicity, bulk, particle density, pellet dimensional stability, and pellet density. However, the pellet tensile strength decreased as the torrefaction severity increased. Therefore, to enhance the tensile strength of the pellets, the introduction of a binder was necessary. Torrefaction liquid and sawdust were used as additives at different proportions during pelletization. The addition of binders (torrefaction liquid and sawdust) to the pellet formulation increased the tensile strength of the torrefied WSS by approximately 50%. The OH groups in the biomass break down to a limited degree due to dehydration. This hinders the formation of H bonds, thereby increasing the chances that the pretreated biomass will become hydrophobic. The Scanning Electron Microscope (SEM) graphs showed that the torrefied WSS pellets demonstrated more firmly glued surfaces with fewer pores spaces when set side by side with the raw pellets. The thermogravimetric analysis conducted showed that the torrefaction of WSS slightly reduced its thermal stability.
Technoeconomic analysis of six case scenarios (wood pellet production from raw sawdust in a pellet plant (I), straw pellet production from raw oat straw in a pellet plant (II), integrated torrefied treated sawdust pelletization plant utilizing the torrefaction liquid (TL) as the pellet binder (III), integrated torrefied treated oat straw pelletization plant utilizing the torrefaction liquid (TL) as a pellet binder (IV), integrated steam treated sawdust pellet plant (V), and integrated steam treated oat straw pellet plant (VI)) was carried out to develop a process model for pellet production from sawdust and oat straw that uses torrefaction and steam explosion pretreatments prior to pelletization. The breakdown of equipment purchase cost showed that the torrefaction reactor is the most expensive unit with about 51% of the purchase cost. Scenarios 1, 2, 5, and 6 generated positive net present value at baseline model. Facility-dependent and feedstock costs were the major significant contributors to the pellet production cost. The minimum selling price of pellets obtained from Scenarios 1-6 were $113.4/t, $118.7/t, $283.4/t $298.7/t, $200.5/t, and $208.4/t, respectively. The profitability of pellet production as determined by the net present value (NPV), internal rate of return (IRR), and payback period was found to be sensitive to variations in feedstock cost.
Description
Keywords
Torrefaction, Steam explosion, pelletization, biofuel, oat straw, sawdust, microwave, tensile strength, technoeconomic analysis.
Citation
Degree
Doctor of Philosophy (Ph.D.)
Department
Chemical and Biological Engineering
Program
Biological Engineering