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Mercury partitioning in super-permafrost groundwater, Truelove Lowland, Devon Island, Nunavut

dc.contributor.advisorSiciliano, Stevenen_US
dc.contributor.committeeMemberSi, Bing C.en_US
dc.contributor.committeeMemberPeak, J. Dereken_US
dc.contributor.committeeMemberKnight, J. Dianeen_US
dc.contributor.committeeMemberFleming, Ian R.en_US
dc.creatorDickson, Alanna Len_US
dc.date.accessioned2008-07-19T15:50:26Zen_US
dc.date.accessioned2013-01-04T04:45:46Z
dc.date.available2009-07-23T08:00:00Zen_US
dc.date.available2013-01-04T04:45:46Z
dc.date.created2008en_US
dc.date.issued2008en_US
dc.date.submitted2008en_US
dc.description.abstractThe objective of this study was to determine the dominant biogeochemical controls on mercury partitioning in super-permafrost groundwater at Truelove Lowland, Devon Island, Nunavut. Mercury partitioning in snow, ephemeral standing water, and super-permafrost groundwater was investigated. Results indicate that partitioning differs between matrices, and that particulate mercury is spatially and temporally dynamic in Truelove Lowland groundwater. Particulate mercury in groundwater was 73 % of total mercury, while snow had only 22 % particulate mercury. Particulate mercury in groundwater rose by over 20 % from Julian day 181 to 189, and decreased slightly on Julian day 191. No single geochemical parameter was a good predictor of particulate mercury concentrations. To expand upon the findings of the field study a laboratory microcosm study was conducted to determine whether certain biogeochemical processes influence mercury partitioning in super-permafrost groundwater. Particulate mercury in the dissimilatory iron reducing bacteria inhibited microcosm was 61 % of total mercury, approximately 18 % lower than in all other treatments. Iron (III) concentrations had a positive correlation with particulate mercury while chloride concentrations had a negative correlation with particulate mercury. Sulfate reducing bacteria were not found to influence mercury partitioning.en_US
dc.identifier.urihttp://hdl.handle.net/10388/etd-07192008-155026en_US
dc.language.isoen_USen_US
dc.subjectmercuryen_US
dc.subjectpartitioningen_US
dc.subjectsuper-permafrosten_US
dc.subjectgroundwateren_US
dc.subjectArcticen_US
dc.titleMercury partitioning in super-permafrost groundwater, Truelove Lowland, Devon Island, Nunavuten_US
dc.type.genreThesisen_US
dc.type.materialtexten_US
thesis.degree.departmentSoil Scienceen_US
thesis.degree.disciplineSoil Scienceen_US
thesis.degree.grantorUniversity of Saskatchewanen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Science (M.Sc.)en_US

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